How to Draw in Photoshop: Sketching Tutorial
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USE 300 NOT 3000 pixels per inch!
And use a tablet!
I should also like to point out I do NOT endorse torrenting photoshop. A lot of people worked very hard to make the software and the least you can do is pay them copious amounts of cash for the privilege to use it. That and it stops you being plucked from your bed by government goons.