A photoelectric material having work function ϕ₀ is illuminated with light of wavelength λ (λ is less than hc/ϕ₀). The fastest photoelectron has a de-Broglie wavelength λₔ. A change in the wavelength of the incident light by Δλ results in change Δλₔ in Δλ. Then, the ratio Δλₔ/Δλ is proportional to:
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